Friday, June 8, 2012

The information of N-Nitroiminoimidazolidine



N-Nitroiminoimidazolidine
Chinese name: 2 – nitro amino Imidazolidine,
Synonyms: 2 – nitro Amino-Imidazolidine; 2 – the NOx amino-Δ21, 3 – diaza-cyclopentene; N-nitro amine imidazolidine; nitro amine imidazolidine; nitro-amino imidazolidine
English name: 2-Nitroaminoimidazoline
Synonyms: 4,5-dihydro-of n-nitro-1h-imidazol-2-amine;-Nitroaminoimidazoline; 2 – (NITROIMINO) IMIDAZOLIDINE; 4,5-dihydro-n-nitro-1h-imidazol-2-amin; 1H-Imidazol-2-amine, 4,5-dihydro-N-nitro-; N-NITROIMINO IMIDAZOLIDINE; 4,5-DIHYDRO-N-NITRO-1H-IMIDAZOL-2-AMINES; 2-NITROAMINOIMIDAZOLINE [FOR IMIDACLOPRID];N-Nitroiminoimidazolidine
CAS No.: 5465-96-3
Molecular formula: C3H6N4O2
Molecular Weight: 130.11
Melting point: 220 ° C
Chemical properties
The imidazolidine pure white crystal, mp213 ~ 215 ° C (decomposition), industrial white or light yellow powder Assay ≥ 98.0%, slightly soluble in cold water, soluble in hot water.
Use
N-nitro the amino imidazolidine referred Imidazolidine, the intermediates of the insecticide imidacloprid; used as intermediates of the efficiency and low toxicity pesticide imidacloprid
Production methods
Preparation of the cyclization of N-nitro-N-imidazolidine nitroguanidine and ethylene diamine.
Nitroguanidine and lye added in the reactor, adding ethylenediamine and 30% of industrial hydrochloric acid at 0 ° C, the suspension of the formation of salt, slowly heated to 60 ° C, the reaction 0.5h immediately transferred to pre-cooling the reactor, crystallization, centrifugal filtration, drying, get Imidazolidine.
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